制備導電聚合物-半導體納米顆粒自組裝膜

Using layer-by-layer self-assembly technique,we have successfully constructed nanostructured composite films of conjugated polymer (sulfonic acid ring substituted polyaniline, SPAn)/ semiconductor nanoparticles(Q-CdS).The processes synthesis have been studied by UV-Vis, contact angle measurement, XPS and AFM techniques.The results indicated that the self-assembly processes were dependent on the pH of the solution of each component and the doping time.It has been found that the roughness of the assembled nano-composite films increases as the layer number increases.The main reason can be attributed to the generation of adsorption defects from partially adsorbed film surface in film fabrication processes.

作 者： 李東升 呂功煊 Li Dong-Sheng LU Gong-xuan   作者單位： 中國科學院蘭州化學物理研究所  刊 名： 物理化學學報  ISTIC SCI PKU 英文刊名： ACTA PHYSICO-CHIMICA SINICA  年，卷(期)： 2001 17(3)  分類號： O64  關鍵詞： 逐層自組裝   納米結構復合膜   制備  

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