Effect of Reduction Temperature on Hydrofining Performance of Supported Molybdenum Phosphide Catalyst

A series of supported molybdenum phosphide catalysts were prepared by impregnation method.XRD, TG-DTG, XPS and BET were used to study the phase, compositions and surface areas of the prepared catalysts. A model reactant containing thiophene, pyridine and cyclohexene was used for the measurements of catalytic activities. The effect of reduction temperature on catalytic activities was investigated. The analysis results by XRD and BET are very different when the reduction temperature is changed from 400 to 900 ℃. MoP/γ-Al2O3 catalysts and CoMoP/γ-Al2O3 catalysts prepared at the reduction temperature of 500 ℃ are the most active ones.

作 者： Fengyan Li Zhifang Zhao Qingjie Li Tianbo Zhao Cuiqing Li Guida Sun   作者單位： Fengyan Li,Zhifang Zhao,Qingjie Li,Cuiqing Li,Guida Sun(Department of Applied Chemistry, Beijing Institute of Petrochemical Technology, Beijing 102617, China)

Tianbo Zhao(School of Science, Beijing Institute of Technology, Beijing 100081, China) 

刊 名： 天然氣化學（英文版）  ISTIC SCI 英文刊名： JOURNAL OF NATURAL GAS CHEMISTRY  年，卷(期)： 2005 14(4)  分類號： O6  關鍵詞： molybdenum phosphide   reduction temperature   hydrodenitrogenation   hydrodesulfurization   supported catalyst  

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