Electrochemical Behavior of Methanol Influenced by Polyaniline Incorporated with Ferrocenesulfonic-carboxylic Acid

After the synthesis of polyaniline in the presence of ferrocenesulfoniccarboxylic acid, its influence on the electrochemical reaction of methanol was studied. The result indicates that the ferrocenyl in ferrocenesulfoniccarboxylic acid plays an important role in the electrocatalytic oxidation of methanol. CH3OH is adsorbed on PANI-Fc before its electrocatalytic oxidation. When the concentration of methanol is 2 mol/L, it begins to be oxidized. The effect of scan rate on the electrochemical reaction of methanol was also studied and 5 mV/s was favourable. It is another method to insert a metal catalyst in polyaniline without its electrodeposition.

作 者： NDAMANISHA Jean Chrysostome WANG Hui GUO Li-ping   作者單位： Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China  刊 名： 高等學校化學研究（英文版）  ISTIC SCI 英文刊名： CHEMICAL RESEARCH IN CHINESE UNIVERSITIES  年，卷(期)： 2005 21(4)  分類號： O6  關鍵詞： Polyaniline   Ferrocenesulfonic-carboxylic acid   Methanol   Electrooxidation   Catalyst  

【Electrochemical Behavior of Methanol】相關文章：

Biological removal of methanol from process condensate for the purpose of reclamation04-26

Children learn best by observing the behavior of adults and05-04

Electrochemical remediation of copper contaminated kaolinite by conditioning anolyte and catholyte pH simultaneously04-26

Effects of methamidophos and glyphosate on copper sorption-desorption behavior in soils04-25

A study of factors influencing consumers behavior in recycling waste household electronic appliances04-26

NOVEL POLYPYRROLE MICROSTRUCTURES GENERATED BY DIRECT ELECTROCHEMICAL OXIDATION OF PYRROLE ON p-TYPE SILICON SUBSTRATE04-27

Long Time Behavior of the Cahn-Hilliard Equation with Irregular Potentials and Dynamic Boundary Conditions04-26

Photodegradation mechanism of two dyes:the influence of adsorption behavior on the novel TiO2 particles04-26

Chemical characteristics of aerosols at coastal station in Hong Kong.Ⅱ.Environmental behavior of trace elements during t04-26