Synthesis, Structure and Characterization of Manganese(Ⅱ) Coordination Polymer with Camphoric Acid and 1,10-Phenanthroli

A novel coordination polymer, Mn(H2O)(CA)(Phen)·H2O(CA=camphoric acid, Phen=1,10-phenanthroline), was synthesized and its crystal structure was determined by single crystal X-ray diffraction. Six-coordinated Mn(Ⅱ) atoms are linked with carboxyl groups from camphoric acid ligands to form infinite one-dimensional chains. These chains are packed by means of hydrogen bonding and π-π stacking, forming a three-dimensional structure. IR, thermogravimetric analysis and magnetic susceptibility data for Mn(H2O)(CA)(Phen)·H2O are given.

作 者： HOU Ying SHI Zhan YANG Ming LI Guang-Hua FENG Shou-Hua   作者單位： State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China  刊 名： 高等學校化學研究（英文版）  ISTIC SCI 英文刊名： CHEMICAL RESEARCH IN CHINESE UNIVERSITIES  年，卷(期)： 2005 21(4)  分類號： O6  關鍵詞： Coordination polymer,Camphoric acid,1,10-Phenanroline,Magnetic property,Crystal structure  

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