Synthesis and Crystal Structures of the α and β Forms of Bis(salicylaldoxime)copper(Ⅱ) Complexes

Modified α and β bis(salicylaldoxime)copper(Ⅱ) have been obtained by recrystallization from ethyl acetate(CCDC Nos. 212157 & 212158). The X-ray analysis reveals that the two modificated forms have the same structure with different geometric parameters. The α form crystallizes in the P2(1)/c space group and the β form in the P1 space group. Both the crystal structures consist of centrosymmetric monomeric molecules of Cu(OC6H4CNOH)2. The IR spectra are in agreement with the structural data.

作 者： WAN Jun WANG Shi-ying WEN Yong-hong YE Su-juan OUYANG Ping-kan ZHANG Shu-sheng   作者單位： WAN Jun(College of Life Science and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing 210093, P. R. China;College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China)

WANG Shi-ying,WEN Yong-hong,YE Su-juan,ZHANG Shu-sheng(College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China)

OUYANG Ping-kan(College of Life Science and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing 210093, P. R. China) 

刊 名： 高等學校化學研究（英文版）  ISTIC SCI 英文刊名： CHEMICAL RESEARCH IN CHINESE UNIVERSITIES  年，卷(期)： 2005 21(4)  分類號： O6  關鍵詞： Copper(Ⅱ) complexes   Salicylaldoxime   X-ray analysis   Crystal structures  

【Synthesis and Crystal Structures of 】相關文章：

Synthesis and Crystal Structure of Binuclear Copper(Ⅱ)Complex Containing (Dimethylaminomethyl)ferrocene04-27

Synthesis and Crystal Structure of 1,4-Bis(2-hydroxymethylphenyl)-1,4-dioxabutane04-27

Synthesis and Crystal Structure of N,N-Diphenyl-3,6-diethyl-1,4-dihydro-s-tetrazine-1,4-dicarbonamide04-26

Syntheses and Crystal Structures of Two Mononuclear Tin(IV) Complexes Derived from Sn(edt)2 (edt = Ethane-1,2-dithiolate04-26

Synthesis and Crystal Structure of 1-(Trifluoromethyl)-1-(propioloyl)-(E)-3-oxo-(2-thienyl)-(2-naphthylamine)04-26

Category Theoretic Properties of Topological Structures and Proximity Structures on L-fuzzy Space04-26

Synthesis of 4-Aminosalicylglycine04-26

Study on synthesis of polylactide from kitchen garbage04-25

Progress in modeling of fluid flows in crystal growth processes04-26

Synthesis of nanosize MnO2 and its performence04-27